|
He kept working for hours. Using the same basic approach, he found he could add more electrons to his calculations and derive
the features of more and more complex molecules. The ability to hybridize the physicists' subshells into new orbitals opened
the door to explaining the structure of a number of molecules, such as the bonding pattern found in certain cobalt and platinum
compounds. One by one, under Pauling's pen, the physicists’ quantum mechanics was falling into line with what the chemists
knew to be true.
"I was so excited and happy, I think I stayed up all night, making, writing out, solving the equations, which were so simple
that I could solve them in a few minutes," he remembered. "Solve one equation, get the answer, then solve another equation
about the structure of octahedral complexes such as the ferrocyanide ion in potassium ferrocyanide, or square planar complexes
such as in tetrachloroplatinate ion, and various other problems. I just kept getting more and more euphorious as time went
by."
|